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海洋环境中技术关键要素的蓬勃影响。

Bourgeoning impact of the technology critical elements in the marine environment.

机构信息

Department of Chemistry, Kuwait University, Khaldiya Campus, Safat, 13060, Kuwait.

Department of Chemistry, Kuwait University, Khaldiya Campus, Safat, 13060, Kuwait.

出版信息

Environ Pollut. 2020 Oct;265(Pt A):115064. doi: 10.1016/j.envpol.2020.115064. Epub 2020 Jun 24.

Abstract

Contamination of the Technology Critical Elements (TCE) through e-wastes and beach plastic wastes are some of the attributes to the recent rise in marine pollution. A generalized study of pollutants in the marine waters showed no evidence of the effect of TCE. However, an in-depth study revealed the mean TCE concentrations in the sequence of gallium (Ga) > thallium (Tl) > niobium (Nb) > tellurium (Te) > tantalum (Ta) > germanium (Ge) > indium (In) in wastewater (0.38 ng.L) >sediment (0.3 ng g) e-wastes (0.29 ng g) > coastal water (0.26 ng.L) > plastic wastes (0.133 ng g) >fish (0.13 ng g). The mean site-wise analysis of all the samples showed high TCE during winter than in the summer seasons as well, in the sequence of Site-II>Site-I>Site-V>Site-IV>Site-III. The mean distribution coefficient (K) of TCE was high in the summer (1.95) than during the winter (1.60) seasons but, the reverse seasonal effects were observed with the bioavailability (%BA) and geo-accumulation index (I). This index quantified TCE in e-wastes and plastic materials. Furthermore, these indicators labeled TCE as one among the sources for 'Fish Kill,' a futuristic threat to seafood consumers and a biomonitoring tool to marine pollution.

摘要

电子废物和海滩塑料废物对技术关键要素 (TCE) 的污染是海洋污染最近上升的一些原因。对海洋水中污染物的综合研究表明没有 TCE 影响的证据。然而,一项深入的研究表明,在废水 (0.38ng.L) > 沉积物 (0.3ng.g) 电子废物 (0.29ng.g) > 沿海水 (0.26ng.L) > 塑料废物 (0.133ng.g) > 鱼 (0.13ng.g) 中 TCE 的浓度顺序为镓 (Ga) > 铊 (Tl) > 铌 (Nb) > 碲 (Te) > 钽 (Ta) > 锗 (Ge) > 铟 (In)。所有样品的平均现场分析表明,冬季的 TCE 含量高于夏季,顺序为 Site-II>Site-I>Site-V>Site-IV>Site-III。TCE 的平均分布系数 (K) 在夏季 (1.95) 高于冬季 (1.60) 季节,但生物可利用性 (%BA) 和地质累积指数 (I) 则出现相反的季节效应。该指数量化了电子废物和塑料材料中的 TCE。此外,这些指标将 TCE 标记为“鱼类死亡”的来源之一,这是对海鲜消费者的未来威胁,也是海洋污染的生物监测工具。

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