School of Safety Science and Emergency Management, Wuhan University of Technology, Wuhan, 430070, China.
School of Safety Science and Emergency Management, Wuhan University of Technology, Wuhan, 430070, China.
J Hazard Mater. 2021 Feb 5;403:123653. doi: 10.1016/j.jhazmat.2020.123653. Epub 2020 Aug 13.
In this investigation, ammonium polyphosphate (APP) is applied to suppress the deflagration of sucrose dust. Through the systematic research on flame propagation images and temperature, decomposition behavior of powder samples and the compositions of deflagration residue, the suppression performance and mechanism of APP on sucrose deflagration are profoundly summarized. Timing diagrams show that APP contributes to reduce deflagration flame brightness, increases ignition delay time and flame fault area. The minimum inerting concentration of APP for sucrose deflagration is determined to be 8 %. From the collected deflagration flame temperature curves, it is confirmed that APP can delay peak temperature arrival time, weaken temperature fluctuation, and decrease peak values of flame temperature and temperature rising rate. Through the analysis on thermal decomposition of samples and deflagration residue, it is reflected that APP has superior composite suppression effect. It can not only absorb reaction heat, but also decrease deflagration exotherm to improve thermal stability of sucrose particles. Thus, the easily oxidized components in sucrose are protected, and deflagration intensity is effectively weakened. This work provides a new solution for prevention and suppression deflagration of dust waste in sugar industry.
在本研究中,采用聚磷酸铵(APP)抑制蔗糖粉尘的爆炸。通过对火焰传播图像和温度、粉末样品分解行为以及爆炸残留物成分的系统研究,深入总结了 APP 对蔗糖爆炸的抑制性能和机制。时程图表明,APP 有助于降低爆炸火焰亮度,增加点火延迟时间和火焰故障面积。确定 APP 对蔗糖爆炸的最小惰性浓度为 8%。从收集的爆炸火焰温度曲线可以确认,APP 可以延迟峰值温度到达时间、减弱温度波动,并降低火焰温度和温度上升率的峰值。通过对样品和爆炸残留物的热分解分析,表明 APP 具有优异的复合抑制效果。它不仅可以吸收反应热,还可以降低爆炸放热,提高蔗糖颗粒的热稳定性。从而保护蔗糖中易氧化的成分,有效减弱爆炸强度。这项工作为糖业粉尘废物爆炸的预防和抑制提供了新的解决方案。