Effect of carbon hybridization in C-F bond as an electron donor in triel bonds.

The ability of the F atom of HC≡CF, HC=CHF and HCCHF to serve as an electron donor to the triel (Tr) atom of TrR in the context of a triel bond is assessed by ab initio calculations. The triel bond formed by C-F is strongest, as high as 30 kcal/mol, followed by C-F, and then by C-F whose triel bonds can be as small as 1 kcal/mol. The noncovalent bond strength diminishes in the order Tr = Al > Ga > B, consistent with the intensity of the π-hole above the Tr atom in the monomer. The triel bond strength of the Al and Ga complexes increases along with the electronegativity of the R substituent but is largest for R=H when Tr=B. Electrostatics play the largest role in the stronger triel bonds, but dispersion makes an outsized contribution for the weakest such bonds.