通过从纳米相分离的聚环氧乙烷-双（三氟甲基磺酰）亚胺锂聚合物电解质薄膜中提取烃模板提高导电性

Enhanced Conductivity via Extraction of Hydrocarbon Templates from Nanophase-Separated PEO-LiOTf Polymer Electrolyte Films.

作者信息

Ostrander John W, Wang Lei, Ali Kizi Teljan, Dajani Jana A, Carr Austin V, Teeters Dale, Lamar Angus A

机构信息

Department of Chemistry and Biochemistry, The University of Tulsa, 800 S. Tucker Dr., Tulsa, Oklahoma 74104, United States.

Department of Chemistry, Hanover College, 517 Ball Drive, Hanover, Indiana 47243, United States.

出版信息

ACS Omega. 2020 Aug 7;5(32):20567-20574. doi: 10.1021/acsomega.0c02794. eCollection 2020 Aug 18.

A series of poly(ethylene oxide)-LiOTf electrolyte films were prepared using a variety of hydrocarbon templates as nanofillers, resulting in observable nanophase separation in the polymer electrolyte. Upon partial extraction of the nanofiller template, an enhanced conductivity over 2 orders of magnitude was measured using ac impedance. Scanning electron microscopy, differential scanning calorimetry, and thermogravimetric analysis were employed to characterize the porosity, composition, and mass loss of template-extracted and nonextracted film samples.