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通过高分辨魔角旋转核磁共振(HR-MAS NMR)和脉冲场梯度核磁共振(PFG-NMR)研究κ-卡拉胶凝胶对肉桂醛释放的抑制作用。

Study on release suppression of cinnamaldehyde from κ-carrageenan gel by HR-MASNMR and pulsed field gradient NMR (PFG-NMR).

作者信息

Yamada Yasumasa, Shizuma Motohiro

机构信息

Department of Food Science and Human Nutrition, Faculty of Food Culture and Human Nutrition, Baika Women's University, 2-19-5 Shukunosho, Ibaraki City, Osaka, 567-8578, Japan.

Department of Biochemistry, Osaka Research Institute of Industrial and Scientific Technology (ORIST), 1-6-50 Morinomiya, Joto-ku, Osaka, 536-8553, Japan.

出版信息

Food Hydrocoll. 2021 Jan;110:106130. doi: 10.1016/j.foodhyd.2020.106130. Epub 2020 Jul 9.

DOI:10.1016/j.foodhyd.2020.106130
PMID:32834337
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7347355/
Abstract

Aiming toward the production and characterization of delicious and functional gel foods, this communication studies the flavor release from cinnamon-containing κ-carrageenan gel. Cinnamaldehyde, which provides the flavor of cinnamon, was released in a trace amount from the gel and detected by flame ionization detector gas chromatography. The retention of cinnamaldehyde in κ-carrageenan gel and the interaction between flavor and polysaccharide were investigated by high-resolution magic-angle spinning nuclear magnetic resonance (HR-MAS NMR) and pulsed-field gradient NMR (PFG NMR). The intact cinnamaldehyde in the gel was also observed by HR-MAS NMR. The relative mobility difference of the flavor and polysaccharide molecules was observed from the diffusion-ordered NMR spectrum of PFG NMR.

摘要

为了生产美味且具有功能性的凝胶食品并对其进行表征,本通讯研究了含肉桂的κ-卡拉胶凝胶中的风味释放。提供肉桂风味的肉桂醛从凝胶中微量释放,并通过火焰离子化检测器气相色谱法进行检测。通过高分辨率魔角旋转核磁共振(HR-MAS NMR)和脉冲场梯度核磁共振(PFG NMR)研究了肉桂醛在κ-卡拉胶凝胶中的保留情况以及风味与多糖之间的相互作用。通过HR-MAS NMR还观察到了凝胶中完整的肉桂醛。从PFG NMR的扩散排序核磁共振谱中观察到了风味分子和多糖分子的相对迁移率差异。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4d12/7347355/0c14c2cfcad3/gr5_lrg.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4d12/7347355/67237cb9e007/fx1_lrg.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4d12/7347355/4ac20c50e8ae/gr1_lrg.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4d12/7347355/d17ca0d91b43/gr2_lrg.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4d12/7347355/19aba3d9f8b1/gr3_lrg.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4d12/7347355/5d825136f6c1/gr4_lrg.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4d12/7347355/0c14c2cfcad3/gr5_lrg.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4d12/7347355/67237cb9e007/fx1_lrg.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4d12/7347355/4ac20c50e8ae/gr1_lrg.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4d12/7347355/d17ca0d91b43/gr2_lrg.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4d12/7347355/19aba3d9f8b1/gr3_lrg.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4d12/7347355/5d825136f6c1/gr4_lrg.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4d12/7347355/0c14c2cfcad3/gr5_lrg.jpg

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本文引用的文献

1
Do Cinnamon Supplements Have a Role in Glycemic Control in Type 2 Diabetes? A Narrative Review.肉桂补充剂在 2 型糖尿病的血糖控制中是否有作用?一篇叙述性综述。
J Acad Nutr Diet. 2016 Nov;116(11):1794-1802. doi: 10.1016/j.jand.2016.07.015. Epub 2016 Sep 8.
2
Magic angle spinning NMR spectroscopy: a versatile technique for structural and dynamic analysis of solid-phase systems.魔角旋转核磁共振光谱法:一种用于固相系统结构和动力学分析的通用技术。
Anal Chem. 2015 Jun 2;87(11):5458-69. doi: 10.1021/ac504288u. Epub 2015 Apr 9.
3
Cinnamon extract improves fasting blood glucose and glycosylated hemoglobin level in Chinese patients with type 2 diabetes.
肉桂提取物可改善中国 2 型糖尿病患者的空腹血糖和糖化血红蛋白水平。
Nutr Res. 2012 Jun;32(6):408-12. doi: 10.1016/j.nutres.2012.05.003. Epub 2012 Jun 14.
4
Assessment of diffusion coefficients of general solvents by PFG-NMR: investigation of the sources error.采用脉冲场梯度核磁共振法评估通用溶剂的扩散系数:源误差研究
J Magn Reson. 2006 Jun;180(2):266-73. doi: 10.1016/j.jmr.2006.03.003. Epub 2006 Mar 24.
5
K(+) and Na(+) effects on the gelation properties of kappa-Carrageenan.钾离子(K⁺)和钠离子(Na⁺)对κ-卡拉胶凝胶特性的影响。
Biophys Chem. 2005 Feb 1;113(2):129-35. doi: 10.1016/j.bpc.2004.08.005.