Gutsev Gennady L, McPherson Shane L, López Peña Hugo A, Boateng Derrick Ampadu, Gutsev Lavrenty G, Ramachandran B Ramu, Tibbetts Katharine Moore
Department of Physics, Florida A&M University, Tallahassee, Florida 32307, United States.
Department of Chemistry, Virginia Commonwealth University, Richmond, Virginia 23284, United States.
J Phys Chem A. 2020 Sep 17;124(37):7427-7438. doi: 10.1021/acs.jpca.0c06545. Epub 2020 Sep 3.
Dissociation pathways of singly- and multiply charged gas-phase nitromethane cations were investigated with strong-field laser photoionization mass spectrometry and density functional theory computations. There are multiple isomers of the singly charged nitromethane radical cation, several of which can be accessed by rearrangement of the parent CH-NO structure with low energy barriers. While direct cleavage of the C-N bond from the parent nitromethane cation produces NO and CH, rearrangement prior to dissociation accounts for fragmentation products including NO, CHOH, and CHNO. Extensive Coulomb explosion in fragment ions observed at high laser intensity indicates that rapid dissociation of multiply charged nitromethane cations produces additional species such as CH, H, and NO. On the basis of analysis of Coulomb explosion in the mass spectral signals and pathway calculations, sufficiently intense laser fields can remove four or more electrons from nitromethane.
