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用于锂离子电池阳极的黑磷/还原氧化石墨烯中稳定共价键的构建

Constructing stable covalent bonding in black phosphorus/reduced graphene oxide for lithium ion battery anodes.

作者信息

Shi Yang, Yi Zhibin, Kuang Yanping, Guo Hanyu, Li Yingzhi, Liu Chen, Lu Zhouguang

机构信息

Department of Materials Science and Engineering, Guangdong Provincial Key Laboratory of Energy Materials for Electric Power, Southern University of Science and Technology, Shenzhen 518055, P. R. China.

出版信息

Chem Commun (Camb). 2020 Oct 7;56(78):11613-11616. doi: 10.1039/d0cc03698f. Epub 2020 Sep 1.

Abstract

Strong covalent bonds were in situ constructed in a unique black phosphorus (BP) @ reduced graphene oxide nanocomposite via a facile and scalable high energy ball-milling process, which contributes to the high specific capacity of BP@irGO and tackles the long-standing problem of large volume expansion of high capacity electrode matrerials.

摘要

通过简便且可扩展的高能球磨工艺,在独特的黑磷(BP)@还原氧化石墨烯纳米复合材料中原位构建了强共价键,这有助于提高BP@rGO的比容量,并解决了高容量电极材料长期存在的大体积膨胀问题。

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