Beloglazkina Elena K, Bogatova Tatiana V, Nenajdenko Valentine G
Department of Chemistry, M. V. Lomonosow Moscow State University, Leninskie gory 1-3, Moscow, 119991, Russia.
Angew Chem Int Ed Engl. 2020 Nov 16;59(47):20744-20752. doi: 10.1002/anie.202005233. Epub 2020 Sep 3.
This Essay outlines the life path and scientific achievements of Nikolai Zelinsky to testify to his contributions to organic chemistry, catalysis, and petrochemistry. His legacy includes four name reactions (the Hell-Volhard-Zelinsky reaction, 1887; the Zelinsky-Stadnikov reaction, 1906; Zelinsky irreversible catalysis, 1911; the Zelinsky-Kazansky acetylene trimerization, 1924), pioneering contributions to the main oil-refining processes (thermal cracking, catalytic cracking, hydrodesulfurization, reforming, and oxidative regeneration of coked catalysts), the coal gas mask, Pd/C and other supported catalysts, and a very large scientific school.
本文概述了尼古拉·泽林斯基的人生轨迹和科学成就,以证明他对有机化学、催化和石油化学的贡献。他的遗产包括四个命名反应(1887年的赫尔-福尔哈德-泽林斯基反应;1906年的泽林斯基-斯塔德尼科夫反应;1911年的泽林斯基不可逆催化;1924年的泽林斯基-卡赞斯基乙炔三聚反应)、对主要炼油工艺(热裂解、催化裂化、加氢脱硫、重整和焦化催化剂的氧化再生)的开创性贡献、煤气面罩、钯/碳及其他负载型催化剂,以及一个非常庞大的科学流派。