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中国沿海城市亚微米气溶胶的化学组成和来源:2017 年金砖国家峰会研究结果。

Chemical composition and sources of submicron aerosol in a coastal city of China: Results from the 2017 BRICS summit study.

机构信息

Center for Excellence in Regional Atmospheric Environment, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China; Key Laboratory of Urban Environment and Health, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China; University of Chinese Academy of Sciences, Beijing 100086, China.

Center for Excellence in Regional Atmospheric Environment, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China; Key Laboratory of Urban Environment and Health, Institute of Urban Environment, Chinese Academy of Sciences, Xiamen 361021, China.

出版信息

Sci Total Environ. 2020 Nov 1;741:140470. doi: 10.1016/j.scitotenv.2020.140470. Epub 2020 Jun 24.

Abstract

Chemical compositions of non-refractory submicron aerosol (NR-PM) were measured via an Aerodyne Aerosol Chemical Speciation Monitor at the coastal city Xiamen during the 2017 BRICS summit from August 10 to September 10. Mean hourly concentration of NR-PM was 13.55 ± 8.83 μg m during the study period, decreasing from 18.83 μg m before-BRICS to 13.02 μg m in BRCIS I and 8.42 μg m in BRICS II. Positive matrix factor analyses resolved four organic aerosols (OA): a hydrocarbon-like OA (HOA, 14.78%), a cooking-related OA (COA, 28.21%), a biomass burning OA (BBOA, 18.00%), and an oxygenated OA (OOA, 39.22%). The contributions of local pollutants like nitrate and HOA reduced, while the proportions of sulfate and OOA increased during the control episodes. The diurnal patterns of NR-PM species and OA components in each episode were characterized. The results showed that BC, nitrate, COA, and HOA had peaks in the morning and evening, which became less obvious under the emission control. Moreover, the diurnal variations of all species in Ep 3 with emission control were much flatter due to the effect of transport. Backward trajectories analysis confirmed the long-range transport of air masses from the continent, which resulted in the high proportions of sulfate (43.69%) and OOA (50.28%) in Ep 3. Our study implies the significant effect of emission control on reducing primary pollutants, but the formation of particles during the long-range transport need to be paid more attention when set the air quality control strategies in coastal cities.

摘要

在 2017 年金砖国家峰会期间(8 月 10 日至 9 月 10 日),我们在沿海城市厦门使用 Aerodyne 气溶胶化学谱仪测量了非难熔亚微米气溶胶(NR-PM)的化学成分。研究期间,NR-PM 的小时平均浓度为 13.55±8.83μg/m,在金砖国家峰会前从 18.83μg/m 下降到 BRICS I 期间的 13.02μg/m 和 BRICS II 期间的 8.42μg/m。正定矩阵因子分析(PMF)解析出了 4 种有机气溶胶(OA):一种烃类 OA(HOA,14.78%)、一种烹饪相关 OA(COA,28.21%)、一种生物质燃烧 OA(BBOA,18.00%)和一种含氧 OA(OOA,39.22%)。在控制期,本地污染物(如硝酸盐和 HOA)的贡献减少,而硫酸盐和 OOA 的比例增加。各阶段 NR-PM 物种和 OA 成分的日变化特征。结果表明,BC、硝酸盐、COA 和 HOA 均在早晚出现峰值,在排放控制下这些峰值变得不那么明显。此外,由于传输的影响,第 3 阶段所有物种的日变化幅度变得更加平坦。后向轨迹分析证实了来自大陆的空气团的长距离传输,这导致第 3 阶段硫酸盐(43.69%)和 OOA(50.28%)的比例较高。我们的研究表明,排放控制对减少一次污染物有显著影响,但在制定沿海城市空气质量控制策略时,需要更加关注长距离传输过程中颗粒的形成。

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