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低水灰比制备的水泥净浆和砂浆的CO养护效率

CO Curing Efficiency for Cement Paste and Mortars Produced by a Low Water-to-Cement Ratio.

作者信息

Han Seong Ho, Jun Yubin, Shin Tae Yong, Kim Jae Hong

机构信息

Department of Civil and Environmental Engineering, Korea Advanced Institute of Science and Technology, Daejeon 34141, Korea.

出版信息

Materials (Basel). 2020 Sep 2;13(17):3883. doi: 10.3390/ma13173883.

Abstract

Curing by CO is a way to utilize CO to reduce greenhouse gas emissions. Placing early-age cement paste in a CO chamber or pressure vessel accelerates its strength development. Cement carbonation is attributed to the quickened strength development, and CO uptake can be quantitatively evaluated by measuring CO gas pressure loss in the pressure vessel. A decrease in CO gas pressure is observed with all cement pastes and mortar samples regardless of the mix proportion and the casting method; one method involves compacting a low water-to-cement ratio mix, and the other method comprises a normal mix consolidated in a mold. The efficiency of the CO curing is superior when a 20% concentration of CO gas is supplied at a relative humidity of 75%. CO uptake in specimens with the same CO curing condition is different for each specimen size. As the specimen scale is larger, the depth of carbonation is smaller. Incorporating colloidal silica enhances the carbonation as well as the hydration of cement, which results in contributing to the increase in the 28-day strength.

摘要

利用一氧化碳进行养护是一种利用一氧化碳减少温室气体排放的方法。将早期水泥浆体置于一氧化碳室或压力容器中可加速其强度发展。水泥碳化归因于强度发展加快,并且可以通过测量压力容器中一氧化碳气体压力损失来定量评估一氧化碳吸收量。无论配合比和浇筑方法如何,所有水泥浆体和砂浆样品均观察到一氧化碳气体压力下降;一种方法是压实低水灰比混合料,另一种方法是在模具中固结普通混合料。当在75%的相对湿度下供应20%浓度的一氧化碳气体时,一氧化碳养护的效率更高。在相同的一氧化碳养护条件下,不同尺寸的试件一氧化碳吸收量不同。随着试件尺寸增大,碳化深度减小。掺入胶体二氧化硅可增强水泥的碳化和水化,从而有助于提高28天强度。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a469/7503678/886e7250ab05/materials-13-03883-g001.jpg

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