Departamento de Química, LABINC, Universidade Federal de Santa Catarina (UFSC), Florianópolis, Santa Catarina 88040-900, Brazil.
Instituto Federal de Educação, Ciência e Tecnologia de Santa Catarina - IFSC, Campus Florianópolis, Santa Catarina 88020-300, Brazil.
Inorg Chem. 2020 Sep 21;59(18):13078-13090. doi: 10.1021/acs.inorgchem.0c00638. Epub 2020 Sep 9.
The new luminescent carbonyl compounds [Mn(Oxa-H)(CO)Br] () and [Mn(Oxa-NMe)(CO)Br] () were synthesized and fully characterized. Complexes and showed CO release under blue light (λ). Spectroscopic techniques and TD-DFT and SOC-TD-DFT calculations indicated that and release the Oxa-H and Oxa-NMe coligands in addition to the carbonyl ligands, increasing the luminescence during photoinduction.
新型发光羰基化合物Mn(Oxa-H)(CO)Br和Mn(Oxa-NMe)(CO)Br被合成并进行了全面表征。配合物和在蓝光（λ）下释放 CO。光谱技术和 TD-DFT 及 SOC-TD-DFT 计算表明，除了羰基配体外，和还释放出 Oxa-H 和 Oxa-NMe 配体，在光诱导过程中增加了发光。
