MXene-based ultra-thin film for terahertz radiation shielding.

We have successfully fabricated Ti-based MXenes flakes, TiCT, by chemical etching, then prepared it as an organic dispersion and finally spin-coated it on polyimide plastic substrate for terahertz wave shielding. The shielding effectivity of the 12 μm ultra-thin film can reach up to 17 dB measured by the terahertz time-domain spectra. We can attribute the excellent phenomenon to the intrinsic absorption of triple-layered TiC, due to the similar double-peak type refraction curves, which have been respectively observed from the experimental samples and the simulation ones. High conductivity and strong THz absorption indicate the TiCT MXene is the absorptive electromagnetic shielding material. Comparing with other kinds of THz shielding materials, the Ti-based MXenes might be a potential candidate for the next generation of ultra-thin and lightweight THz shielding.