Miller R, Alahverdjieva V S, Fainerman V B
Max-Planck-Institut für Kolloid- und Grenzflächenforschung, Am Mühlenberg 14424, Potsdam, Germany.
Medical Physicochemical Centre, Donetsk Medical University, 16 Ilych Avenue, 83003 Donetsk, Ukraine.
Soft Matter. 2008 May 14;4(6):1141-1146. doi: 10.1039/b802034e.
The behaviour of mixed protein-surfactant surface layers at liquid interfaces has been described essentially qualitatively, until only very recently thermodynamic models were derived for interfacial layers formed by proteins and non-ionic or ionic surfactants, which represent the basis also for a quantitative understanding of the respective adsorption dynamics and dilational rheology of liquid interfaces. On the basis of experimental data obtained from single drop and bubble studies and optical methodologies like ellipsometry and BAM, a clear picture can be drawn now about liquid surface layers relevant for a broad field of applications.
直到最近才推导出蛋白质与非离子或离子表面活性剂形成的界面层的热力学模型，在此之前，液体界面处混合蛋白质 - 表面活性剂表面层的行为基本上只是定性描述。这些模型也是定量理解液体界面各自吸附动力学和扩张流变学的基础。基于从单滴和气泡研究以及椭圆偏振仪和BAM等光学方法获得的实验数据，现在可以清晰地描绘出与广泛应用领域相关的液体表面层的情况。
