Ahmadvand Hassan, Iraji Zad Azam, Mohammadpour Raheleh, Hosseini-Shokouh Seyed Hossein, Asadian Elham
Institute for Nanoscience and Nanotechnology, Sharif University of Technology, 14588, Tehran, Iran.
Department of Physics, Sharif University of Technology, 14588, Tehran, Iran.
Sci Rep. 2020 Sep 9;10(1):14799. doi: 10.1038/s41598-020-71695-3.
Here in this research, room temperature ethanol and humidity sensors were prepared based on two dimensional (2D) hybrid nanostructures of tungsten di-sulfide (WS) nanosheets and graphene oxide nanoribbons (GONRs) as GOWS. The characterization results based on scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (ESD), Raman spectroscopy and X-ray diffraction (XRD) analysis confirmed the hybrid formations. Ethanol sensing of drop-casted GOWS films on SiO substrate indicated increasing in gas response up to 5 and 55 times higher compared to pristine GONRs and WS films respectively. The sensing performance of GOWS hybrid nanostructures was investigated in different concentrations of WS, and the highest response was about 126.5 at 1 ppm of ethanol in 40% relative humidity (R.H.) for WS/GONRs molar ratio of 10. Flexibility of GOWS was studied on Kapton substrate with bending radius of 1 cm, and the gas response decreased less than 10% after 30th bending cycles. The high response and flexibility of the sensors inspired that GOWS are promising materials for fabrication of wearable gas sensing devices.
在本研究中,基于二硫化钨(WS)纳米片和氧化石墨烯纳米带(GONRs)的二维(2D)混合纳米结构(即GOWS)制备了室温乙醇和湿度传感器。基于扫描电子显微镜(SEM)、能量色散X射线光谱(ESD)、拉曼光谱和X射线衍射(XRD)分析的表征结果证实了混合结构的形成。在SiO衬底上滴铸的GOWS薄膜的乙醇传感表明,与原始GONRs和WS薄膜相比,气体响应分别提高了5倍和55倍。研究了不同WS浓度下GOWS混合纳米结构的传感性能,对于WS/GONRs摩尔比为10的情况,在40%相对湿度(R.H.)下,乙醇浓度为1 ppm时,最高响应约为126.5。在弯曲半径为1 cm的Kapton衬底上研究了GOWS的柔韧性,在第30次弯曲循环后,气体响应下降不到10%。传感器的高响应性和柔韧性表明,GOWS是用于制造可穿戴气体传感设备的有前途的材料。