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水热碳化法对经萃取预处理后的食物垃圾进行处理:对水热炭燃料特性、燃烧行为以及钠和钾去除行为的研究。

Hydrothermal carbonization of food waste after oil extraction pre-treatment: Study on hydrochar fuel characteristics, combustion behavior, and removal behavior of sodium and potassium.

机构信息

Institute of Energy and Power Engineering, Zhejiang University of Technology, Hangzhou 310014, China; State Key Laboratory of Clean Energy Utilization, Zhejiang University, Zheda Road 38, Hangzhou 310027, China.

Institute of Energy and Power Engineering, Zhejiang University of Technology, Hangzhou 310014, China.

出版信息

Sci Total Environ. 2021 Feb 1;754:142192. doi: 10.1016/j.scitotenv.2020.142192. Epub 2020 Sep 3.

Abstract

This study aims to convert oil extracted food waste (OEFW) into hydrochar as potential solid fuel via hydrothermal carbonization (HTC) process. The effect of HTC temperature and residence time on the physicochemical characteristic, combustion behavior, and the removal behavior of sodium and potassium were evaluated. The raw OEFW material was successfully converted into energy densified hydrochar with higher high heating value (HHV) (21.13-24.07 MJ/kg) and higher fuel ratio (0.112-0.146). In addition, carbon content in hydrochar increased to 46.92-51.82% after HTC at various operating conditions. Compared with OEFW, the hydrochar had more stable and longer combustion process with the higher ignition temperature and burnout temperature. Besides, the HTC process showed high removal rates of sodium and potassium. It was found that the HTC temperature resulted in a significant reduction of sodium and potassium in hydrochar as compared to the residence time. The highest removal rate of sodium (70.98%) and potassium (84.05%) was obtained. Overall, the results show that the HTC is a promising alternative for conventional technologies (e.g., incineration and landfill) for treatment and energy conversion of OEFW.

摘要

本研究旨在通过水热碳化(HTC)工艺将从食用油废弃物(OEFW)中提取的油转化为水热炭,作为潜在的固体燃料。考察了 HTC 温度和停留时间对其物理化学特性、燃烧行为以及钠和钾去除行为的影响。结果表明,原始 OEFW 材料成功地转化为具有更高高热值(HHV)(21.13-24.07MJ/kg)和更高燃料比(0.112-0.146)的能源密集型水热炭。此外,在不同操作条件下进行 HTC 后,水热炭中的碳含量增加到 46.92-51.82%。与 OEFW 相比,水热炭具有更稳定、更长的燃烧过程,具有更高的着火温度和燃尽温度。此外,HTC 工艺对钠和钾具有较高的去除率。结果表明,与停留时间相比,HTC 温度导致水热炭中钠和钾的去除率显著降低。获得了最高的钠去除率(70.98%)和钾去除率(84.05%)。总体而言,研究结果表明,HTC 是处理和能源转化 OEFW 的传统技术(如焚烧和填埋)的一种有前途的替代方法。

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