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含活性炭泡沫复合材料的孔隙结构特征

Pore Structure Characteristics of Foam Composite with Active Carbon.

作者信息

Lee Jungsoo, Choi Young Cheol

机构信息

Department of Civil and Environmental Engineering, Gachon University, Seongnam 13120, Korea.

出版信息

Materials (Basel). 2020 Sep 11;13(18):4038. doi: 10.3390/ma13184038.

Abstract

Characterization of porous materials is essential for predicting and modeling their adsorption performance, strength, and durability. However, studies on the optimization of the pore structure to efficiently remove pollutants in the atmosphere by physical adsorption of construction materials have been insufficient. This study investigated the pore structure characteristics of foam composites. Porous foam composites were fabricated using foam composite with high porosity, open pores, and palm shell active carbon with micropores. The content was substituted 5%, 10%, 15%, and 20% by volume of cement. From the measured nitrogen adsorption isotherm, the pore structure of the foam composite was analyzed using the Brunauer-Emmett-Teller (BET) theory, Barrett-Joyner-Halenda (BJH) analysis, and Harkins-jura adsorption isotherms. From the analysis results, it was found that activated carbon increases the specific surface area and micropore volume of the foam composite. The specific surface area and micropore volume of the foam composite containing 15% activated carbon were 106.48 m/g and 29.80 cm/g, respectively, which were the highest values obtained in this study. A foam composite with a high micropore volume was found to be effective for the adsorption of air pollutants.

摘要

多孔材料的表征对于预测和模拟其吸附性能、强度及耐久性至关重要。然而,关于通过建筑材料的物理吸附来优化孔隙结构以有效去除大气中污染物的研究尚不充分。本研究对泡沫复合材料的孔隙结构特征进行了调查。使用具有高孔隙率、开孔以及带有微孔的棕榈壳活性炭的泡沫复合材料来制备多孔泡沫复合材料。其含量按水泥体积的5%、10%、15%和20%进行替代。根据测得的氮气吸附等温线,运用布鲁诺尔-埃米特-泰勒(BET)理论、巴雷特-乔伊纳-哈伦达(BJH)分析以及哈金斯-尤拉吸附等温线对泡沫复合材料的孔隙结构进行了分析。从分析结果发现,活性炭增加了泡沫复合材料的比表面积和微孔体积。含15%活性炭的泡沫复合材料的比表面积和微孔体积分别为106.48 m²/g和29.80 cm³/g,这是本研究中获得的最高值。发现具有高微孔体积的泡沫复合材料对空气污染物的吸附有效。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5379/7558174/7fc84029e6a7/materials-13-04038-g001.jpg

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