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惰性气体CO对CH/CO爆燃压力的影响。

Effect of Inert Gas CO on Deflagration Pressure of CH/CO.

作者信息

Luo Zhenmin, Su Yang, Li Ruikang, Chen Xiaokun, Wang Tao

机构信息

Xi'an University of Science and Technology, Xi'an, Shaanxi Province 710000, China.

出版信息

ACS Omega. 2020 Sep 3;5(36):23002-23008. doi: 10.1021/acsomega.0c02686. eCollection 2020 Sep 15.

Abstract

To study the effect of CO on the explosion characteristics of CH/CO, the explosion experiments of the effect of different volume fractions of CO on CH/CO deflagration were carried out by using the self-developed pipeline gas explosion experimental platform. The explosion characteristics of premixed gas are studied from the aspects of explosion peak pressure and time of reaching the peak pressure. The results show that the effect of CO on the deflagration of methane with a different volume fraction is the result of the interaction of the elementary reaction and the oxygen content in the reaction system. Two percent of the CO promoted the methane explosion in the oxygen-rich state, while it showed a damping effect in the oxygen-poor state. CO has different inhibitory effects on different volume fractions of methane. Experiments show that the addition of 20% CO can effectively inhibit the deflagration of methane. The addition of CO has a stronger inhibitory effect on the mixed gas of CH/CO under the condition of poor oxygen but less on the mixed gas under the condition of rich oxygen.

摘要

为研究CO对CH/CO爆炸特性的影响,利用自行研制的管道气体爆炸实验平台,开展了不同体积分数CO对CH/CO爆燃影响的爆炸实验。从爆炸峰值压力和达到峰值压力的时间等方面研究了预混气体的爆炸特性。结果表明,CO对不同体积分数甲烷爆燃的影响是基元反应与反应体系中氧含量相互作用的结果。2%的CO在富氧状态下促进了甲烷爆炸,而在贫氧状态下则表现出抑制作用。CO对不同体积分数的甲烷有不同的抑制作用。实验表明,添加20%的CO可有效抑制甲烷爆燃。在贫氧条件下,添加CO对CH/CO混合气体的抑制作用更强,而在富氧条件下对混合气体的抑制作用较弱。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fcf0/7495721/4128047f33c4/ao0c02686_0002.jpg

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