铂(II)配合物诱导碳杂卟啉(3.1.1)生成β-β'稠合二聚体及其单体类似物。
PtCl mediated peripheral transformation of carbatriphyrin(3.1.1) into a -fused β-β' dimer and its monomer analogue.
机构信息
School of Chemical Sciences, National Institute of Science Education and Research (NISER), HBNI, Bhubaneswar-752050, Odisha, India.
出版信息
Chem Commun (Camb). 2020 Oct 22;56(84):12809-12812. doi: 10.1039/d0cc05309k.
PMID:32966387
Abstract
An unprecedented formation of a meso-fused β-β' carbaporphyrin dimer and its monomer with a keto group was described. These analogues were synthesized from carbatriphyrin(3.1.1.) by a metal assisted strategy using PtCl2 salt in a single step without any prefunctionalized precursors. Upon dimerization, the monomeric ligand with a dianionic core is transformed into a dimeric structure with unique trianionic cores.
摘要
描述了一种前所未有的中-β'-碳氮卟啉二聚体及其酮基单体的形成。这些类似物是通过使用 PtCl2 盐的金属辅助策略，从碳三嗪(3.1.1.)一步合成的，无需任何预官能化前体。二聚化后，具有二价核的单体配体转变为具有独特三价核的二聚体结构。
Zotero 插件