Recent Advances in the Design and Syntheses of Porphyrinoids by Embedding Higher Analogues of Arene and Pyridine Units.

Due to enthralling applications in various fields and augmenting fundamental wisdom, π-conjugated macrocycles in general and porphyrin systems in particular are constantly explored. Subtle modifications of porphyrin structure can amend the rudimentary properties. Pursuing innovative properties provides impetus to underpin arene or pyridine moiety embedded porphyrin derivatives. There have been several reviews related to arene incorporated carbaporphyrinoids; however, recent developments of porphyrin analogues by introducing higher analogues of arenes and pyridine units are not adequately inspected. This mini-review mainly focuses on biphenyl, bipyridine, terphenyl, and mixed arene pyridine embedded porphyrin analogues and their coordination chemistry.