Xiong Ting-Kai, Li Xue-Jun, Zhang Min, Liang Ying
School of Life and Environmental Sciences, Guilin University of Electronic Technology, Guilin, Guangxi 541004, People's Republic of China.
Org Biomol Chem. 2020 Oct 14;18(39):7774-7788. doi: 10.1039/d0ob01590c.
In this review, recent progress in the application of CO2 as an electrophilic reagent and nitrogen as a nucleophilic center under different catalytic conditions in organic synthesis is summarized. The used catalytic methods in the reactions of CO2 and nitrogen are classified as metal catalysis, metal-free catalysis, photocatalysis and electrocatalysis. Various catalytic conditions have been used to solve the problems of thermodynamic properties and stability of CO2. The transformation mechanisms of these reactions are discussed.
在本综述中，总结了二氧化碳作为亲电试剂和氮作为亲核中心在不同催化条件下于有机合成中的应用进展。二氧化碳与氮反应中所使用的催化方法分为金属催化、无金属催化、光催化和电催化。已采用各种催化条件来解决二氧化碳的热力学性质和稳定性问题。并讨论了这些反应的转化机理。
