Faverio Chiara, Boselli Monica Fiorenza, Medici Fabrizio, Benaglia Maurizio
Dipartimento di Chimica, Università degli Studi di Milano, Via Golgi 19, 20133 Milano, Italy.
Org Biomol Chem. 2020 Oct 14;18(39):7789-7813. doi: 10.1039/d0ob01351j.
Ammonia borane NH3·BH3 is considered a promising material for hydrogen storage and release, and is attracting increasing attention as a relatively inexpensive, atom economy-convenient and viable reagent for developing new green synthetic transformations. The present review offers a wide overview on the use of AB in the reduction of organic compounds, and highlights the versatility of this reagent, due to the possibility of modulating its activity employing different strategies, which include the use of transition metals, p-block species, organocatalysts and FLP systems.
氨硼烷NH₃·BH₃被认为是一种很有前景的储氢和释氢材料，并且作为一种相对廉价、原子经济性便利且可行的试剂，在开发新的绿色合成转化方面正吸引着越来越多的关注。本综述广泛概述了氨硼烷在有机化合物还原中的应用，并强调了该试剂的多功能性，这是因为可以采用不同策略来调节其活性，这些策略包括使用过渡金属、p区元素、有机催化剂和FLP体系。
