Pradhan Santanu, Dalmases Mariona, Konstantatos Gerasimos
ICFO-Institut de Ciències Fotòniques, The Barcelona Institute of Science and Technology, Castelldefels, Barcelona, 08860, Spain.
ICREA-Institució Catalana de Recerca i Estudis Avançats, Passeig Lluís Companys 23, Barcelona, 08010, Spain.
Adv Mater. 2020 Nov;32(45):e2003830. doi: 10.1002/adma.202003830. Epub 2020 Sep 30.
Solid-state broadband light emitters in the visible have revolutionized today's lighting technology achieving compact footprints, flexible form factors, long lifetimes, and high energy saving, although their counterparts in the infrared are still in the development phase. To date, broadband emitters in the infrared have relied on phosphor-downconverted light emitters based on atomic optical transitions in transition metal or rare earth elements in the phosphor layer resulting in limited spectral bandwidths in the near-infrared and preventing their integration into electrically driven light-emitting diodes (LEDs). Herein, phosphor-converted LEDs based on engineered stacks of multi-bandgap colloidal quantum dots (CQDs) are reported as a novel class of broadband emitters covering a broad short-wave infrared (SWIR) spectrum from 1050-1650 nm with a full-width-half-maximum of 400 nm, delivering 14 mW of optical power with a quantum efficiency of 5.4% and power conversion efficiency of 13%. Leveraging the electrical conductivity of the CQD stacks, further, the first broadband SWIR-active LED is demonstrated, paving the way toward complementary metal-oxide-semiconductor integrated broadband emitters for on-chip spectrometers and low-cost volume manufacturing. SWIR spectroscopy is employed to illustrate the practical relevance of the emitters in food and material identification case studies.
固态可见光宽带发光体彻底改变了当今的照明技术,实现了紧凑的占地面积、灵活的外形、长寿命和高节能,尽管它们在红外领域的同类产品仍处于开发阶段。迄今为止,红外宽带发光体依赖于基于磷光体层中过渡金属或稀土元素的原子光学跃迁的磷光体下转换发光体,这导致近红外光谱带宽有限,并阻碍它们集成到电驱动发光二极管(LED)中。在此,报道了基于工程化多带隙胶体量子点(CQD)堆叠的磷光体转换LED,这是一类新型宽带发光体,覆盖1050 - 1650 nm的宽短波红外(SWIR)光谱,半高宽为400 nm,输出14 mW的光功率,量子效率为5.4%,功率转换效率为13%。此外,利用CQD堆叠的导电性,展示了首个宽带SWIR有源LED,为用于片上光谱仪和低成本批量制造的互补金属氧化物半导体集成宽带发光体铺平了道路。采用SWIR光谱来阐述发光体在食品和材料识别案例研究中的实际应用价值。