Department of Chemistry, Graduate School of Science, and Integrated Research Consortium on Chemical Sciences (IRCCS), Nagoya University, Furo, Chikusa, Nagoya, 464-8602, Japan.
Chem Commun (Camb). 2020 Oct 27;56(85):12901-12904. doi: 10.1039/d0cc05255h.
Seeded supramolecular polymerization of cystine-based dimeric diamides with aromatic substituents at the C- and N-termini was achieved in aqueous media. Theoretical and spectroscopic studies reveal that the terminal groups play crucial roles in slowing spontaneous assembly through formation of a folded conformation and guiding molecular alignment in the aggregated state.
在水相介质中，实现了带有芳香取代基的 C-和 N-末端二酰胺的胱氨酸二聚体的有种子的超分子聚合。理论和光谱研究表明，末端基团通过形成折叠构象来减缓自发组装，并在聚集态中引导分子排列，从而在缓慢的自组装中起着至关重要的作用。
