Bettoni Léo, Gaillard Sylvain, Renaud Jean-Luc
Normandie Univ., LCMT, ENSICAEN, UNICAEN, CNRS, 6 Boulevard du Maréchal Juin, 14000 Caen, France.
Chem Commun (Camb). 2020 Oct 27;56(85):12909-12912. doi: 10.1039/d0cc05840h.
Herein we report a diaminocyclopentadienone iron tricarbonyl complex catalyzed synthesis of substituted cyclopentane, cyclohexane and cycloheptane compounds using the borrowing hydrogen strategy in the presence of various substituted primary and secondary 1,n diols as alkylating reagents. Deuterium labeling experiments confirm that the diols were the hydride source in this cascade process.
在此，我们报道了一种二氨基环戊二烯酮三羰基铁配合物催化的反应，该反应在各种取代的伯醇和仲醇作为烷基化试剂存在的情况下，采用借氢策略合成取代的环戊烷、环己烷和环庚烷化合物。氘标记实验证实，二醇是该串联过程中的氢化物来源。
