-氨基吡啶叶立德导向、铜促进的芳烃C-H键硫属化反应
-Aminopyridinium Ylide-Directed, Copper-Promoted Chalcogenation of Arene C-H Bonds.
作者信息
Nguyen Hanh, Daugulis Olafs
机构信息
Department of Chemistry, University of Houston, Houston, Texas 77204-5003, United States.
出版信息
J Org Chem. 2020 Oct 16;85(20):13069-13079. doi: 10.1021/acs.joc.0c01757. Epub 2020 Oct 1.
Abstract
-Aminopyridinium ylide-directing group is employed for copper-promoted chalcogenation of sp C-H bonds with aryl and alkyl disulfides as well as diphenyl diselenide. Reactions proceed in hexafluoroisopropanol (HFIP) solvent at elevated temperatures and are promoted by copper(II) acetate.
摘要
-氨基吡啶叶立德导向基团用于铜促进的sp C-H键与芳基和烷基二硫化物以及二苯基二硒醚的硫族化反应。反应在六氟异丙醇（HFIP）溶剂中于高温下进行，并由醋酸铜（II）促进。
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