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实验测量和钙、钾氯化物三元溶液黏度和密度的建模。

Experimental measurements and modelling of viscosity and density of calcium and potassium chlorides ternary solutions.

机构信息

Department of Chemical Engineering, College of Engineering, Qatar University, Doha, Qatar.

Central Laboratory Unit, Qatar University, Doha, Qatar.

出版信息

Sci Rep. 2020 Oct 1;10(1):16312. doi: 10.1038/s41598-020-73484-4.

Abstract

Measured viscosity and density data for ternary aqueous solutions of CaCl and KCl are presented at temperatures between 293 and 323 K with 5 K increment. A modified Jones-Dole was introduced by adding extra terms and proved to be suitable for modelling of the viscosity data. Goldsack and Franchetto, Hu and Exponential models are used to correlate the viscosity data, too. Al models are correlated as a function of temperature and concentration. All models had successfully predicted the viscosity with high precision reaching a maximum average absolute deviation (AAD) of less than 2.3%. The modified Jones-Dole showed the best results among other models. Viscosity of the ternary solution is higher than the viscosity of water by about 15% at low concentrations and reaches about 270% at the highest concentrations. The amount of CaCl has more significant effect on the ternary mixture viscosity compared to KCl. This has created difficulty in measuring the viscosity and consequently the challenge in finding the different models parameters. Ternary solution densities were successfully correlate with Kumar's model with AAD of less than 0.4%. Comparison of the ternary solution density and viscosity with the few available data literature showed a good agreement.

摘要

本文呈现了在 293 至 323 K 温度范围内,以 5 K 为增量的 CaCl 和 KCl 三元水溶液的实测粘度和密度数据。通过添加额外项,引入了改进的 Jones-Dole 方程,并证明其适用于粘度数据的建模。此外,还使用了 Goldsack 和 Franchetto、Hu 和指数模型来关联粘度数据。所有模型都被关联为温度和浓度的函数。所有模型都成功地以高精度预测了粘度,最大平均绝对偏差(AAD)小于 2.3%。改进的 Jones-Dole 模型在其他模型中表现最好。在低浓度下,三元溶液的粘度比水高约 15%,在最高浓度下达到约 270%。与 KCl 相比,CaCl 的含量对三元混合物的粘度有更显著的影响。这给粘度的测量带来了困难,因此也给寻找不同模型参数带来了挑战。Kumar 模型成功地关联了三元溶液的密度,平均绝对偏差(AAD)小于 0.4%。与少数可用文献中的三元溶液密度和粘度进行比较,结果表明具有良好的一致性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3db0/7530761/bc7b05de03fd/41598_2020_73484_Fig1_HTML.jpg

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