Causal factors for pesticide trends in streams of the United States: Atrazine and deethylatrazine.

Pesticides are important for agriculture in the United States, and atrazine is one of the most widely used and widely detected pesticides in surface water. A better understanding of the mechanisms by which atrazine and its degradation product, deethylatrazine, increase and decrease in surface waters can help inform future decisions for water quality improvement. This study considers causal factors for trends in pesticide concentration in U.S. streams and models the causal factors, other than use, in structural equation models. The structural equation models use a concomitant trend in corn (Zea mays L.) and a latent variable model, indicating moisture supply and management. The moisture supply and management latent variable model incorporates long-term moisture conditions in the individual watersheds by using the Palmer hydrologic drought index, human influence on the hydrologic cycle through the percentage of the watershed drained by tile drains in 2012, and the base-flow contribution to streamflow, using the base-flow index. The structural equation models explain 77 and 38% of the variability in atrazine and deethylatrazine trends, respectively, across the conterminous United States. The models highlight future water quality challenges, particularly in tile-drained settings where fall precipitation and heavy precipitation are increasing.