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聚氨酯与聚丙烯酰胺混合黏性土的干裂特性

Desiccation Cracking Behavior of Polyurethane and Polyacrylamide Admixed Clayey Soils.

作者信息

Qi Changqing, Bai Yuxia, Liu Jin, Bu Fan, Kanungo Debi Prasanna, Song Zezhuo, He Xilong

机构信息

School of Earth Sciences and Engineering, Hohai University, Nanjing 210098, China.

Council of Scientific and Industrial Research (CSIR)-Central Building Research Institute (CBRI), Roorkee 247667, India.

出版信息

Polymers (Basel). 2020 Oct 18;12(10):2398. doi: 10.3390/polym12102398.

Abstract

There has been a growing interest in polymer applied for soil reinforcement in recent years. However, there little attention has been paid to the effects of polymer on soil cracking behavior, and cracks significantly change soil strength and hydraulic properties and alter reinforcement effectiveness. This study investigated the desiccation cracking behavior of polyurethane (PU) and polyacrylamide (PAM) admixed clayey soils with different polymer concentrations by performing desiccation cracking tests. Scanning electron microscope (SEM) observation was also carried out to obtain the internal structure of these soils. The results show that PU and PAM addition both prolonged the initial evaporation stage, accelerated later evaporation processes, and the effects were related to polymer concentration. Final cracks morphology analyses show that PAM addition slightly reduced the cracking and crushing degree and kept the soil relatively intact, while PU addition slightly enhanced the cracking and crushing degree of soil. In addition, PU and PAM addition both increased the width and length of cracks. The scanning electron microscopy (SEM) analyses show that the effects of polymer on soil evaporation and cracking could be concluded as: (1) storing water in voids, (2) influencing water immigration channel, (3) providing space for soil shrinkage, and (4) enhancing the connection between aggregates, which did not fully come into play because of the existence of hydrogel form. These achievements provide a certain basis for the research of desiccation cracking behavior of polymer treated soil and make significant sense for the safe and effective running of related projects.

摘要

近年来,人们对用于土壤加固的聚合物的兴趣日益浓厚。然而,聚合物对土壤开裂行为的影响却很少受到关注,而裂缝会显著改变土壤强度和水力特性,并改变加固效果。本研究通过进行干燥开裂试验,研究了不同聚合物浓度的聚氨酯(PU)和聚丙烯酰胺(PAM)混合黏土的干燥开裂行为。还进行了扫描电子显微镜(SEM)观察,以获取这些土壤的内部结构。结果表明,添加PU和PAM均延长了初始蒸发阶段,加速了后期蒸发过程,且效果与聚合物浓度有关。最终裂缝形态分析表明,添加PAM略微降低了开裂和破碎程度,使土壤保持相对完整,而添加PU则略微提高了土壤的开裂和破碎程度。此外,添加PU和PAM均增加了裂缝的宽度和长度。扫描电子显微镜(SEM)分析表明,聚合物对土壤蒸发和开裂的影响可归纳为:(1)在孔隙中储存水分;(2)影响水分迁移通道;(3)为土壤收缩提供空间;(4)增强团聚体之间的连接,由于水凝胶形式的存在,这些作用并未完全发挥出来。这些成果为聚合物处理土壤的干燥开裂行为研究提供了一定依据,对相关工程的安全有效运行具有重要意义。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d6c2/7603284/0cb8b79f9a33/polymers-12-02398-g001.jpg

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