Zheng Linfeng, Fan Jinjuan, Gong Qing, Sun Wei, Jia Xinghui
China Helicopter Research and Development Institute, Jingdezhen 333001, China.
AECC Beijing Institute of Aeronautical Materials, Beijing 100095, China.
Polymers (Basel). 2023 Nov 11;15(22):4386. doi: 10.3390/polym15224386.
Polyurethane is widely used on the surface of composite materials for rotor blades as sand erosion protection materials. The failure mechanism investigation of polyurethane film under service conditions is useful for developing the optimal polyurethane film for rotor blades. In this article, the sand erosion test parameters were ascertained according to the service environment of the polyurethane film. The sand erosion resistance and failure mechanism of polyurethane film at different impact angles were analyzed by an infrared thermometer, a Fourier transform infrared spectrometer (FTIR), a differential scanning calorimeter (DSC), a field emission scanning electron microscope (FESEM), and a laser confocal microscope (CLSM). The results show that the direct measurement method of volume loss can better characterize the sand erosion resistance of the polyurethane film compared to traditional mass loss methods, which avoids the influence of sand particles embedded in the polyurethane film. The sand erosion resistance of polyurethane film at low-angle impact is much lower than that at high-angle impact. At an impact rate of 220 m/s, the volume loss after sand erosion for 15 min at the impact angle of 30° is 57.8 mm, while that at the impact angle of 90° is only 2.6 mm. The volume loss prediction equation was established according to the experimental data. During low-angle erosion, the polyurethane film damage is mainly caused by sand cutting, which leads to wrinkling and accumulation of surface materials, a rapid increase in roughness, and the generation of long cracks. The linking of developing cracks would lead to large-scale shedding of polyurethane film. During high-angle erosion, the polyurethane film damage is mainly caused by impact. The connection of small cracks caused by impact leads to the shedding of small pieces of polyurethane, while the change in the roughness of the film is not as significant as that during low-angle erosion. The disordered arrangement of the soft and hard blocks becomes locally ordered under the action of impact and cutting loads. Then, the disordered state is restored after the erosion test finishes. The erosion of sand particles leads to an increase in the temperature of the erosion zone of the polyurethane film, and the maximum temperature rise is 6 °C, which does not result in a significant change in the molecular structure of the polyurethane film. The erosion failure mechanism is cracking caused by sand cutting and impact.
聚氨酯作为防砂蚀材料被广泛应用于复合材料转子叶片表面。研究聚氨酯薄膜在服役条件下的失效机制,有助于开发出适用于转子叶片的最佳聚氨酯薄膜。本文根据聚氨酯薄膜的服役环境确定了砂蚀试验参数。利用红外热成像仪、傅里叶变换红外光谱仪(FTIR)、差示扫描量热仪(DSC)、场发射扫描电子显微镜(FESEM)和激光共聚焦显微镜(CLSM),分析了不同冲击角度下聚氨酯薄膜的抗砂蚀性能及失效机制。结果表明,与传统的质量损失法相比,体积损失直接测量法能更好地表征聚氨酯薄膜的抗砂蚀性能,避免了嵌入聚氨酯薄膜中的砂粒的影响。聚氨酯薄膜在低角度冲击下的抗砂蚀性能远低于高角度冲击下的性能。在冲击速度为220 m/s时,30°冲击角下砂蚀15 min后的体积损失为57.8 mm,而90°冲击角下仅为2.6 mm。根据实验数据建立了体积损失预测方程。在低角度冲蚀过程中,聚氨酯薄膜损伤主要由砂粒切割引起,导致表面材料起皱和堆积,粗糙度迅速增加,并产生长裂纹。扩展裂纹的连接会导致聚氨酯薄膜大规模脱落。在高角度冲蚀过程中,聚氨酯薄膜损伤主要由冲击引起。冲击产生的小裂纹相互连接导致小块聚氨酯脱落,而薄膜粗糙度的变化不如低角度冲蚀时显著。软硬段的无序排列在冲击和切割载荷作用下局部有序化。冲蚀试验结束后,无序状态恢复。砂粒冲蚀导致聚氨酯薄膜冲蚀区温度升高,最大温升为6℃,未导致聚氨酯薄膜分子结构发生显著变化。冲蚀失效机制是由砂粒切割和冲击引起的开裂。