Department of Chemistry, University of Helsinki, P.O. Box 55, FI-00014 Helsinki, Finland.
Gasera Ltd., Lemminkäisenkatu 59, FI-20520 Turku, Finland.
Anal Chem. 2020 Nov 3;92(21):14582-14588. doi: 10.1021/acs.analchem.0c02887. Epub 2020 Oct 21.
Cantilever-enhanced photoacoustic spectroscopy coupled with gas chromatography is used to quantitatively analyze a mixture of alcohols in a quasi-online manner. A full identification and quantification of all analytes are achieved based on their spectral fingerprints using a widely tunable continuous-wave laser as a light source. This can be done even in the case of interfering column/septum bleed or simultaneously eluted peaks. The combination of photoacoustic spectroscopy and gas chromatography offers a viable solution for compact and portable instruments in applications that require straightforward analyses with no consumables.
悬臂增强光声光谱法结合气相色谱法可实现对醇混合物的准在线定量分析。基于其光谱指纹,使用宽调谐连续波激光作为光源,可实现所有分析物的完全识别和定量。即使存在干扰柱/隔垫泄漏或同时洗脱峰的情况,也能做到这一点。光声光谱法和气相色谱法的结合为需要无耗材的简单分析的应用提供了一种可行的解决方案,可用于紧凑、便携式仪器。