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乙烯-醋酸乙烯酯共聚物改性的废旧轮胎橡胶:加工、物理机械性能、挥发性有机化合物排放及回收可能性

Ground Tire Rubber Modified by Ethylene-Vinyl Acetate Copolymer: Processing, Physico-Mechanical Properties, Volatile Organic Compounds Emission and Recycling Possibility.

作者信息

Zedler Łukasz, Burger Paulina, Wang Shifeng, Formela Krzysztof

机构信息

Department of Polymer Technology, Faculty of Chemistry, Gdańsk University of Technology, 80-233 Gdańsk, Poland.

Department of Polymer Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, China.

出版信息

Materials (Basel). 2020 Oct 20;13(20):4669. doi: 10.3390/ma13204669.

Abstract

Ground tire rubber (GTR) was reclaimed and modified with 10 phr of ethylene-vinyl acetate copolymer via low-temperature extrusion process. Processing, physico-mechanical properties, volatile organic compounds emission, and recycling possibility were investigated. In order to better understand the impact of used modifiers, their efficiency was compared with trans-polyoctenamer, which is an additive that is commercially dedicated to waste rubber recycling. The results showed that a relatively small amount of ethylene-vinyl acetate copolymer improves the mechanical properties of modified reclaimed GTR and also allows further recycling by multiple processing without the deterioration of performance after three cycles.

摘要

通过低温挤出工艺,用10份乙烯-醋酸乙烯酯共聚物对废轮胎橡胶(GTR)进行再生和改性。研究了其加工性能、物理机械性能、挥发性有机化合物排放以及回收可能性。为了更好地理解所用改性剂的影响,将它们的效率与反式聚辛烯进行了比较,反式聚辛烯是一种专门用于废橡胶回收的商业添加剂。结果表明,相对少量的乙烯-醋酸乙烯酯共聚物可改善改性再生GTR的机械性能,并且还能通过多次加工实现进一步回收,经过三个循环后性能不会恶化。

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