Department of Analytical Chemistry, Faculty of Chemistry, Gdansk University of Technology, Poland.
Sci Total Environ. 2020 Jun 10;720:137485. doi: 10.1016/j.scitotenv.2020.137485. Epub 2020 Feb 21.
The main focus of this study is the emission of monoaromatic hydrocarbons because these are the preliminary factors of potential solvent and monomer residues present in single-use plastic barbecue and kitchen utensils comprising polystyrene, polypropylene, natural cellulose, and biodegradable polymers intended for use with hot meal or beverages. Herein, the emissions of monoaromatic hydrocarbons (styrene, benzene, toluene, ethylbenzene, and xylene compounds and the total volatile organic compounds (TVOC)) from nine types of disposable plastic utensils are reported. Seventy two samples of single-use plastic utensils were conditioned at 40 and 80 °C using a stationary emission microchamber system. The average TVOC released from the studied polystyrene, polypropylene, and natural or biodegradable utensils were (2.3 ± 1.3), (1.01 ± 0.15), and (0.48 ± 0.37) μg g, respectively, at 40 °C and (11.1 ± 1.2), (46.1 ± 9.5), and (5.5 ± 1.1) μg g, respectively, at 80 °C. Significant emissions of styrene (ranged from 3.5 up to 15.3 × 10 ng∙g), toluene (from 2.8 up to 0.53 × 10 ng∙g), and ethylbenzene (from 3.7 up to 5.7 × 10 ng∙g) from the studied samples were observed, especially at 80 °C. Thus, elevated temperatures increase the potential emission of solvent and monomer residues from plastics and could affect the quality of consumed meals or beverages, such as taste. Additionally, to determine the possible interactions between the measured chemical compounds in the plastic utensils, the Pearson's correlation coefficients were calculated.
本研究的主要重点是单芳香烃的排放,因为这些是存在于一次性塑料烧烤和厨房用具中的潜在溶剂和单体残留的初步因素,这些用具由聚苯乙烯、聚丙烯、天然纤维素和可生物降解聚合物组成,用于热餐或饮料。本文报道了九种一次性塑料器具中单芳香烃(苯乙烯、苯、甲苯、乙苯和二甲苯化合物以及总挥发性有机化合物(TVOC))的排放。72 个一次性塑料器具样品在 40 和 80°C 下使用固定排放微室系统进行调节。研究中的聚苯乙烯、聚丙烯和天然或可生物降解器具分别在 40°C 下释放的平均 TVOC 为(2.3±1.3)、(1.01±0.15)和(0.48±0.37)μg g,在 80°C 下释放的平均 TVOC 为(11.1±1.2)、(46.1±9.5)和(5.5±1.1)μg g。研究样品中还观察到苯乙烯(范围为 3.5 至 15.3×10ng∙g)、甲苯(范围为 2.8 至 0.53×10ng∙g)和乙苯(范围为 3.7 至 5.7×10ng∙g)的大量排放,尤其是在 80°C 时。因此,升高的温度会增加塑料中溶剂和单体残留的潜在排放量,并可能影响所消耗餐食或饮料的质量,例如味道。此外,为了确定塑料器具中测量的化学化合物之间可能存在的相互作用,计算了 Pearson 相关系数。