Key Laboratory of Plant Nutrition and Fertilizer, Ministry of Agriculture and Rural Affairs/Institute of Agricultural Resources and Regional Planning, Chinese Academy of Agricultural Sciences, Beijing, 100081, China.
College of Environmental Sciences, Sichuan Agricultural University, Chengdu Campus, Chengdu, 611130, Sichuan, China.
Sci Rep. 2020 Oct 23;10(1):18207. doi: 10.1038/s41598-020-75192-5.
Mineral soil conditioners (MSCs) are used to regulate soil acidity and improve soil quality; they are often made in sintering potassium feldspar, limestone, or dolomite, and are alkaline materials rich in silicon, calcium, potassium, and magnesium. The key point of how to apply them into farmlands is their ability to adjust soil acidity and the MSCs requirement (MSC). In this study, inductively coupled plasma-optical emission spectroscopy (ICP-OES) analysis and X-ray diffraction (XRD) were firstly used to determine the elemental and phase compositions of the MSCs in order to establish its equivalent relationship for the depletion of soil activity (H) and its conversion relationship with CaCO. Secondly, the soil culture method and the improved Shoemaker Mclean Peatt-Double Buffer (SMP-DB) method were compared using a group of 14 typical acid soils in MSC. It is investigated that the MSCs contained four alkali/alkaline earth-metal elements: Ca, Mg, K, and Na in the bound aluminosilicate form (CaMgAlSiO, Ca(SiO), KAlSiO, and KAlSiO); and the depletion of 2.31 mol of H required 100 g of MSCs and the amount of Si-Ca-K-Mg MSC needed to deplete the same quantity of H was only 0.87 times that of CaCO. Based on the calculations by using the SMP-DB method and the soil culture method, the MSC for treating the 14 typical acid soils were in the range of 0.56-8.27 t hm and 0-10.8 t hm, respectively. Data from both methods were highly correlated with each other and there was a good linear correlation between them, and the equation: [Formula: see text] could be used to calculate the MSCs requirement. The recommended MSC was approximately 4-8, 2-6, and 1-3 t hm when soil pH < 4.50, 4.50 < pH < 5.50, and pH > 5.50, respectively. The experimental and computational methods established in this study could serve as the scientific basis and theoretical guidance for the production and agricultural use of MSCs.
矿物土壤调理剂 (MSC) 用于调节土壤酸度并改善土壤质量;它们通常由烧结钾长石、石灰石或白云石制成,是富含硅、钙、钾和镁的碱性物质。将它们应用于农田的关键是它们调节土壤酸度的能力和 MSC 的需求量(MSC)。在这项研究中,首先使用电感耦合等离子体 - 原子发射光谱法(ICP-OES)分析和 X 射线衍射(XRD)来确定 MSC 的元素和相组成,以建立其与土壤活性(H)消耗的等效关系及其与 CaCO 的转化关系。其次,使用一组 14 种典型的酸性土壤,比较了土壤培养法和改良的 Shoemaker Mclean Peatt-Double Buffer(SMP-DB)法。研究了 MSC 中以束缚态铝硅酸盐形式存在的四种碱/碱土金属元素:Ca、Mg、K 和 Na(CaMgAlSiO、Ca(SiO)、KAlSiO 和 KAlSiO);消耗 2.31 mol H 需要 100 g MSC,消耗等量 H 所需的 Si-Ca-K-Mg MSC 仅为 CaCO 的 0.87 倍。根据 SMP-DB 法和土壤培养法的计算结果,处理 14 种典型酸性土壤的 MSC 用量范围分别为 0.56-8.27 thm 和 0-10.8 thm。两种方法的数据高度相关,具有良好的线性相关性,方程:[Formula: see text]可用于计算 MSC 的需求量。当土壤 pH < 4.50 时,建议 MSC 用量约为 4-8 t·hm;当 4.50 < pH < 5.50 时,建议 MSC 用量约为 2-6 t·hm;当 pH > 5.50 时,建议 MSC 用量约为 1-3 t·hm。本研究建立的实验和计算方法可为 MSC 的生产和农业应用提供科学依据和理论指导。