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空间变化的基底锚定对向列型液晶薄膜不稳定性和去湿的影响。

Effects of spatially-varying substrate anchoring on instabilities and dewetting of thin nematic liquid crystal films.

作者信息

Lam Michael-Angelo Y-H, Kondic Lou, Cummings Linda J

机构信息

U. S. Army Engineer Research and Development Center, Coastal and Hydraulics Laboratory, 3909 Halls Ferry Road, Vicksburg, MS 39180, USA.

出版信息

Soft Matter. 2020 Nov 18;16(44):10187-10197. doi: 10.1039/d0sm01416h.

DOI:10.1039/d0sm01416h
PMID:33103707
Abstract

Partially wetting nematic liquid crystal (NLC) films on substrates are unstable to dewetting-type instabilities due to destabilizing solid/NLC interaction forces. These instabilities are modified by the nematic nature of the films, which influences the effective solid/NLC interaction. In this work, we focus on the influence of imposed substrate anchoring on the instability development. The analysis is carried out within a long-wave formulation based on the Leslie-Ericksen description of NLC films. Linear stability analysis of the resulting equations shows that some features of the instability, such as emerging wavelengths, may not be influenced by the imposed substrate anchoring. Going further into the nonlinear regime, considered via large-scale GPU-based simulations, shows however that nonlinear effects may play an important role, in particular in the case of strong substrate anchoring anisotropy. Our simulations show that instability of the film develops in two stages: the first stage involves formation of ridges that are perpendicular to the local anchoring direction; and the second involves breakup of these ridges and formation of drops, whose final distribution is influenced by the anisotropy imposed by the substrate. Finally, we show that imposing more complex substrate anisotropy patterns allows us to reach basic understanding of the influence of substrate-imposed defects in director orientation on the instability evolution.

摘要

由于固体/向列相液晶(NLC)相互作用力的不稳定,在基底上的部分润湿向列相液晶薄膜对于去湿型不稳定性是不稳定的。这些不稳定性会被薄膜的向列相性质所改变,这会影响有效的固体/NLC相互作用。在这项工作中,我们关注施加的基底锚定对不稳定性发展的影响。分析是在基于NLC薄膜的莱斯利 - 埃里克森描述的长波公式内进行的。对所得方程的线性稳定性分析表明,不稳定性的一些特征,如出现的波长,可能不受施加的基底锚定的影响。然而,通过基于大规模GPU的模拟进一步进入非线性区域表明,非线性效应可能起重要作用,特别是在强基底锚定各向异性的情况下。我们的模拟表明,薄膜的不稳定性分两个阶段发展:第一阶段涉及形成垂直于局部锚定方向的脊;第二阶段涉及这些脊的破裂和液滴的形成,其最终分布受基底施加的各向异性影响。最后,我们表明施加更复杂的基底各向异性图案使我们能够基本了解基底施加的指向矢取向缺陷对不稳定性演化的影响。

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