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用于光催化将二氧化碳还原为甲醇燃料的AgCuInS-石墨烯-TiO三元复合材料的新型微观和纳米结构

Novel Micro and Nanostructure of a AgCuInS-Graphene-TiO Ternary Composite for Photocatalytic CO Reduction for Methanol Fuel.

作者信息

Otgonbayar Zambaga, Cho Kwang Youn, Oh Won-Chun

机构信息

Department of Advanced Materials Science & Engineering, Hanseo University, Seosan-si 356-706, Chungnam, South Korea.

Korea Institute of Ceramic Engineering and Technology, Soho-ro, Jinju-si, Gyeongsangnam-do, South Korea.

出版信息

ACS Omega. 2020 Oct 6;5(41):26389-26401. doi: 10.1021/acsomega.0c02498. eCollection 2020 Oct 20.

Abstract

Photocatalytic CO reduction into hydrocarbon fuels over photocatalysts has hypothetical and reasonably developed into a trendy exploration topic. In this study, the progress of the quaternary nanocomposite containing a graphene-based catalyst was reported; this was fabricated using the hydrothermal technique. The analysis of physical characteristics of the nanocomposite confirmed the interaction between all parts. The quaternary nanocomposite containing the graphene-based catalyst was utilized for carbon dioxide reduction to methanol (CHOH) under light irradiation. Titanium dioxide (TiO) and the quaternary nanocomposite of AgCuInS were monotonously spread on the graphene exterior. This nanomaterial showed superior activity compared with TiO and the binary composite for CO conversion, and the obtained result indicates that the synthesized ternary composite enhaces the properties of the photocatalyst in the reduction process.

摘要

通过光催化剂将光催化CO还原为碳氢燃料已经得到了假设,并合理地发展成为一个热门的探索课题。在本研究中,报道了含石墨烯基催化剂的四元纳米复合材料的进展;该复合材料是采用水热技术制备的。纳米复合材料的物理特性分析证实了各部分之间的相互作用。含石墨烯基催化剂的四元纳米复合材料在光照下用于将二氧化碳还原为甲醇(CH₃OH)。二氧化钛(TiO₂)和AgCuInS的四元纳米复合材料均匀地分布在石墨烯表面。与TiO₂和二元复合材料相比,这种纳米材料在CO转化方面表现出优异的活性,所得结果表明合成的三元复合材料在还原过程中增强了光催化剂的性能。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/777b/7581086/1f27a18ffdab/ao0c02498_0002.jpg

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