Sr_{2}MoO_{4} and Sr_{2}RuO_{4}: Disentangling the Roles of Hund's and van Hove Physics.

Sr_{2}MoO_{4} is isostructural to the unconventional superconductor Sr_{2}RuO_{4} but with two electrons instead of two holes in the Mo/Ru-t_{2g} orbitals. Both materials are Hund's metals, but while Sr_{2}RuO_{4} has a van Hove singularity in close proximity to the Fermi surface, the van Hove singularity of Sr_{2}MoO_{4} is far from the Fermi surface. By using density functional plus dynamical mean-field theory, we determine the relative influence of van Hove and Hund's metal physics on the correlation properties. We show that theoretically predicted signatures of Hund's metal physics occur on the occupied side of the electronic spectrum of Sr_{2}MoO_{4}, identifying Sr_{2}MoO_{4} as an ideal candidate system for a direct experimental confirmation of the theoretical concept of Hund's metals via photoemission spectroscopy.