Wu Hongbo, Hao Liang, Chen Chunhui, Zhou Jianfeng
School of Mechanical and Power Engineering, Nanjing Tech University, Nanjing, 211816 Jiangsu, PR China.
ACS Omega. 2020 Oct 16;5(42):27425-27432. doi: 10.1021/acsomega.0c03857. eCollection 2020 Oct 27.
Considering the severe impacts on the economic losses caused by oil spills, it is of great significance to develop an oil-absorbent material for removing the oil slick from the water surface effectively. As a new oil-absorbent material, magnetorheological fluid (MRF) has unsinkability, hydrophobicity, and lipophilicity, which could effectively remove the oil slick on the water surface while repelling water. Particularly, the prepared MRF shows a good response to external magnetic field. MRFs show high oil removal capacity in fresh water, deionized water, and salt water with efficiencies up to 94.39, 93.65, and 92.71%, respectively. Besides, FeO/OA magnetic nanoparticles (MPs) could be reprepared into MRF by simple treatments. After the fifth cycle, the MRF prepared by the recovered FeO/OA MPs still has high oil removal efficiency, and that means the FeO/OA MPs has excellent reusability and stability. The method for preparing MRFs provided in this work is simple and effective, and the MRFs have a promising potential for cleaning oil slick.
考虑到溢油造成的经济损失的严重影响,开发一种能有效去除水面浮油的吸油材料具有重要意义。作为一种新型吸油材料,磁流变液(MRF)具有不沉性、疏水性和亲油性,能在排斥水的同时有效去除水面浮油。特别是,制备的磁流变液对外加磁场表现出良好的响应。磁流变液在淡水、去离子水和盐水中均表现出高除油能力,效率分别高达94.39%、93.65%和92.71%。此外,通过简单处理,FeO/OA磁性纳米颗粒(MPs)可重新制备成磁流变液。经过第五次循环后,由回收的FeO/OA MPs制备的磁流变液仍具有高除油效率,这意味着FeO/OA MPs具有优异的可重复使用性和稳定性。本文提供的磁流变液制备方法简单有效,磁流变液在清理浮油方面具有广阔的应用前景。