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用于快速高效去除水面浮油的超疏水FeO/OA磁流变液

Superhydrophobic FeO/OA Magnetorheological Fluid for Removing Oil Slick from Water Surfaces Effectively and Quickly.

作者信息

Wu Hongbo, Hao Liang, Chen Chunhui, Zhou Jianfeng

机构信息

School of Mechanical and Power Engineering, Nanjing Tech University, Nanjing, 211816 Jiangsu, PR China.

出版信息

ACS Omega. 2020 Oct 16;5(42):27425-27432. doi: 10.1021/acsomega.0c03857. eCollection 2020 Oct 27.

Abstract

Considering the severe impacts on the economic losses caused by oil spills, it is of great significance to develop an oil-absorbent material for removing the oil slick from the water surface effectively. As a new oil-absorbent material, magnetorheological fluid (MRF) has unsinkability, hydrophobicity, and lipophilicity, which could effectively remove the oil slick on the water surface while repelling water. Particularly, the prepared MRF shows a good response to external magnetic field. MRFs show high oil removal capacity in fresh water, deionized water, and salt water with efficiencies up to 94.39, 93.65, and 92.71%, respectively. Besides, FeO/OA magnetic nanoparticles (MPs) could be reprepared into MRF by simple treatments. After the fifth cycle, the MRF prepared by the recovered FeO/OA MPs still has high oil removal efficiency, and that means the FeO/OA MPs has excellent reusability and stability. The method for preparing MRFs provided in this work is simple and effective, and the MRFs have a promising potential for cleaning oil slick.

摘要

考虑到溢油造成的经济损失的严重影响,开发一种能有效去除水面浮油的吸油材料具有重要意义。作为一种新型吸油材料,磁流变液(MRF)具有不沉性、疏水性和亲油性,能在排斥水的同时有效去除水面浮油。特别是,制备的磁流变液对外加磁场表现出良好的响应。磁流变液在淡水、去离子水和盐水中均表现出高除油能力,效率分别高达94.39%、93.65%和92.71%。此外,通过简单处理,FeO/OA磁性纳米颗粒(MPs)可重新制备成磁流变液。经过第五次循环后,由回收的FeO/OA MPs制备的磁流变液仍具有高除油效率,这意味着FeO/OA MPs具有优异的可重复使用性和稳定性。本文提供的磁流变液制备方法简单有效,磁流变液在清理浮油方面具有广阔的应用前景。

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