Transient Self-assembly Processes Operated by Gaseous Fuels under Out-of-Equilibrium Conditions.

Herein we report transient out-of-equilibrium self-assembly of molecules operated by gaseous fuel mixtures. The combination of an active gaseous chemical fuel and an inert gas or compressed air, which assists the degassing of the gaseous fuel from the solution, drives the transient self-assembly process. The gaseous nature of the fuel as well as the exhaust helps in their easy removal and thereby prevents their accumulation within the system and helps in maintaining the efficiency of the transient self-assembly process. The strategy is executed with a rather simple experimental set up and operates at ambient temperatures. Our approach may find use in the development of smart materials suitable for applications such as temporally active gas sensing and sequestration.