Cai Meng, Ding Sha, Gibbons Bradley, Yang Xiaozhou, Kessinger Matthew C, Morris Amanda J
Department of Chemistry, Virginia Polytechnic Institute and State University, 1040 Drillfield Drive, Blacksburg, Virginia 24061, USA.
Chem Commun (Camb). 2020 Nov 19;56(92):14361-14364. doi: 10.1039/d0cc02206c.
Electrochemical oxidation of 5-hydroxymethylfurfural (HMF) is a promising synthetic route for 2,5-furandicarboxylic acid (FDCA) production. Here, we prepared a nickel(ii)-modified covalent-organic framework (COF) film TpBpy-Ni@FTO for HMF electrooxidation. With a high conversion of HMF (96%), TpBpy-Ni@FTO afforded a 58% FDCA yield. This work underlines the great potential of COF-based materials in electrocatalysis.
5-羟甲基糠醛（HMF）的电化学氧化是生产2,5-呋喃二甲酸（FDCA）的一种很有前景的合成路线。在此，我们制备了用于HMF电氧化的镍（II）修饰的共价有机框架（COF）薄膜TpBpy-Ni@FTO。TpBpy-Ni@FTO实现了HMF的高转化率（96%），FDCA产率达58%。这项工作突出了基于COF的材料在电催化方面的巨大潜力。
