Department of Chemical Engineering, School of Chemical Engineering, Kherad Institute of Higher Education, Bushehr, Iran.
Faculty of Chemical and Petroleum Engineering, University of Tabriz, Tabriz, 5166616471, Iran.
Carbohydr Polym. 2021 Jan 1;251:117085. doi: 10.1016/j.carbpol.2020.117085. Epub 2020 Sep 14.
The effect of chitosan and FeO magnetic nanoparticles on the chromium adsorption property of Moringa oleifera activated carbon (AC) was explored. Various techniques were applied to reveal the properties of adsorbers to absorb chromium ions. A majority of the pollutant was removed at pH2 and 50 min. The kinetic behavior of the chromium uptake process was governed by the pseudo-second-order kinetic model (PSOKM). Based on the thermodynamic investigation, the chromium adsorption using all adsorbers was exothermic and spontaneous. The maximum single-layer adsorption capacity of AC, CS/AC, AC/FeO, and CS/AC/FeO adsorbers was 56.78 mg/g, 114.80 mg/g, 121.70 mg/g, and 130.80 mg/g, respectively. The isotherm constants quantity highlighted that the Cr-adsorption process is optimal and physical. The acquired findings revealed that the modification of AC by chitosan and FeO nanoparticles increased the Cr adsorption. Adsorbers re-used up to 5 stages with a yield >90 %, which indicates that the composites are a promising option for Cr removal.
研究了壳聚糖和 FeO 磁性纳米粒子对辣木活性炭(AC)吸附铬性能的影响。采用多种技术揭示了吸附剂吸附铬离子的性能。在 pH2 和 50 分钟时,大部分污染物被去除。铬的吸附过程动力学行为由准二级动力学模型(PSOKM)控制。根据热力学研究,所有吸附剂的铬吸附都是放热和自发的。AC、CS/AC、AC/FeO 和 CS/AC/FeO 吸附剂的最大单层吸附容量分别为 56.78、114.80、121.70 和 130.80mg/g。等温常数表明,Cr 吸附过程是最佳的物理吸附过程。研究结果表明,壳聚糖和 FeO 纳米粒子对 AC 的修饰提高了 Cr 的吸附性能。吸附剂可重复使用 5 次以上,产率>90%,表明复合材料是去除 Cr 的一种很有前途的选择。