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A Local-Exchange Model of Folding Chain Surface of Polymer Crystal Based on Worm-Like Chain Model within Single-Chain in Mean-Field Theory.

作者信息

Xiao Hongyi, Zhang Xinghua, Yan Dadong

机构信息

Department of Physics, Beijing Normal University, Beijing 100875, China.

School of Science, Beijing Jiaotong University, Beijing 100044, China.

出版信息

Polymers (Basel). 2020 Oct 30;12(11):2555. doi: 10.3390/polym12112555.

Abstract

The structure of amorphous layer of folding surface controls the properties of the polymer lamellar crystal, which consists of chains with a loop conformation. The surface tension depends on the length and the distance between two injection points of the loop which involving the reptation motion and lateral exchange motion of the stems. In the present work, a local-exchange motion model based on the worm-like chain model is developed to investigate the effects of lateral motion of stems on the release the surface tension. The optimal distance between two injection points is determined by the balance of chain bending energy and conformational entropy. The numerical results provide evidences to the adjacent re-entry model for various loop lengths. A possible explanation involving density of injection points is proposed to interpret the mechanism.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e1d4/7693907/f4fb021780be/polymers-12-02555-g001.jpg

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本文引用的文献

1
Crystallization of Bulk Polymers With Chain Folding: Theory of Growth of Lamellar Spherulites.
J Res Natl Bur Stand A Phys Chem. 1961 Jul-Aug;65A(4):297-336. doi: 10.6028/jres.065A.035. Epub 1961 Aug 1.
2
Theory of Formation of Polymer Crystals with Folded Chains in Dilute Solution.
J Res Natl Bur Stand A Phys Chem. 1960 Jan-Feb;64A(1):73-102. doi: 10.6028/jres.064A.007. Epub 1960 Feb 1.
3
Light-responsive expansion-contraction of spherical nanoparticle grafted with azopolymers.
J Chem Phys. 2017 Apr 28;146(16):164901. doi: 10.1063/1.4981914.
5
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J Chem Phys. 2015 Nov 28;143(20):204903. doi: 10.1063/1.4936324.
6
Semiflexible polymer brushes and the brush-mushroom crossover.
Soft Matter. 2015 Apr 7;11(13):2604-16. doi: 10.1039/c4sm02862g.
8
Coil-bridge transition and Monte Carlo simulation of a stretched polymer.
Phys Rev E Stat Nonlin Soft Matter Phys. 2011 Oct;84(4 Pt 1):041809. doi: 10.1103/PhysRevE.84.041809. Epub 2011 Oct 25.
9
Fast and accurate SCFT calculations for periodic block-copolymer morphologies using the spectral method with Anderson mixing.
Eur Phys J E Soft Matter. 2009 Dec;30(4):361-9. doi: 10.1140/epje/i2009-10534-3. Epub 2009 Dec 3.
10
Chain bridging in a model of semicrystalline multiblock copolymers.
J Chem Phys. 2009 Feb 7;130(5):054904. doi: 10.1063/1.3072339.

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