Physical Chemistry, Department of Chemistry, University of Konstanz, Universitätsstrasse 10, D-78457 Konstanz, Germany.
Chem Commun (Camb). 2020 Nov 19;56(92):14439-14442. doi: 10.1039/d0cc04628k.
The citrate-assisted growth of nickel hexacyanoferrate (NiHCF) nanocubes was investigated. Control over the complexation of Ni2+ ions with citrate at different temperatures enabled fine tuning of the nanocrystal (NC) dimensions and their self-assembly into mesocrystals. Our results introduce new concepts towards the synthesis of NiHCF NCs, potentially applicable to other members of the Prussian blue analogues family.
研究了柠檬酸辅助下镍六氰合铁酸盐（NiHCF）纳米立方体的生长。通过控制 Ni2+ 离子与柠檬酸在不同温度下的络合，可以精细调节纳米晶体（NC）的尺寸及其自组装成介晶。我们的研究结果为 NiHCF NC 的合成引入了新概念，可能适用于普鲁士蓝类似物家族的其他成员。
