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用于制备名为富勒烯翅片微柱的独特一维富勒烯晶体的简单退火工艺。

Simple annealing process for producing unique one-dimensional fullerene crystal named fullerene finned-micropillar.

作者信息

Onishi Taku, Tsukamoto Takahiro, Oya Takahide

机构信息

Graduate School of Engineering Science, Yokohama National University, Yokohama, 240-8501, Japan.

Graduate School of Informatics and Engineering, The University of Electro-Communications, Chofu, 182-8585, Japan.

出版信息

Sci Rep. 2020 Nov 6;10(1):19270. doi: 10.1038/s41598-020-76252-6.

DOI:10.1038/s41598-020-76252-6
PMID:33159117
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC7648105/
Abstract

We propose a process for easily fabricating a unique one-dimensional fullerene crystal, i.e., a fullerene finned-micropillar (FFMP). To fabricate a one-dimensional fullerene crystal more easily than when using current processes, fullerene was first annealed at 1173 K for 1 h with an argon gas flow of 0.5 L/min. We then examined how the FFMP structure changed when the fabrication process conditions, such as temperature, annealing time, and argon gas flow rate, were varied. FFMPs can be prepared within a short time and may have the same electrical characteristics as other one-dimensional crystals, e.g., fullerene nanowhiskers, so they are expected to be very useful for field-effect transistors, organic photovoltaics, and so on in the near future.

摘要

我们提出了一种可轻松制造独特的一维富勒烯晶体的方法,即富勒烯翅片微柱体(FFMP)。为了比使用当前方法更轻松地制造一维富勒烯晶体,首先在0.5 L/min的氩气流中于1173 K对富勒烯进行1小时退火。然后,我们研究了在诸如温度、退火时间和氩气流速等制造工艺条件变化时,FFMP结构是如何改变的。FFMP可在短时间内制备出来,并且可能具有与其他一维晶体(如富勒烯纳米须)相同的电学特性,因此预计在不久的将来它们对于场效应晶体管、有机光伏等将非常有用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/77ff/7648105/de2422558986/41598_2020_76252_Fig8_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/77ff/7648105/bb43955a3015/41598_2020_76252_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/77ff/7648105/d005a06d67dc/41598_2020_76252_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/77ff/7648105/a3ef453d0667/41598_2020_76252_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/77ff/7648105/444997c8b2e4/41598_2020_76252_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/77ff/7648105/33ec39ca9cf2/41598_2020_76252_Fig5_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/77ff/7648105/cbde43f47f69/41598_2020_76252_Fig6_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/77ff/7648105/dade399a68ca/41598_2020_76252_Fig7_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/77ff/7648105/de2422558986/41598_2020_76252_Fig8_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/77ff/7648105/bb43955a3015/41598_2020_76252_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/77ff/7648105/d005a06d67dc/41598_2020_76252_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/77ff/7648105/a3ef453d0667/41598_2020_76252_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/77ff/7648105/444997c8b2e4/41598_2020_76252_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/77ff/7648105/33ec39ca9cf2/41598_2020_76252_Fig5_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/77ff/7648105/cbde43f47f69/41598_2020_76252_Fig6_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/77ff/7648105/dade399a68ca/41598_2020_76252_Fig7_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/77ff/7648105/de2422558986/41598_2020_76252_Fig8_HTML.jpg

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本文引用的文献

1
Synthesis of fullerene nanowhiskers using the liquid-liquid interfacial precipitation method and their mechanical, electrical and superconducting properties.采用液-液界面沉淀法合成富勒烯纳米晶须及其机械、电学和超导性能。
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Facile synthesis of highly water-soluble fullerenes more than half-covered by hydroxyl groups.易于合成羟基覆盖度超过一半的高水溶性富勒烯。
ACS Nano. 2008 Feb;2(2):327-33. doi: 10.1021/nn700151z.
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Polymer-fullerene composite solar cells.
聚合物-富勒烯复合太阳能电池。
Angew Chem Int Ed Engl. 2008;47(1):58-77. doi: 10.1002/anie.200702506.
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AFM and XRD investigation of crystalline vapor-deposited C(60) films.对气相沉积C(60)晶体薄膜的原子力显微镜和X射线衍射研究。
Anal Bioanal Chem. 1995 Oct;353(3-4):433-8. doi: 10.1007/s0021653530433.
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Imaging as-grown [60]fullerene nanotubes by template technique.通过模板技术对生长态的[60]富勒烯纳米管进行成像。
J Am Chem Soc. 2002 Nov 13;124(45):13370-1. doi: 10.1021/ja0280527.