Faculty of Engineering and Design, Kagawa University, 2217-20 Hayashi-cho, Takamatsu, Kagawa, 761-0396, Japan.
Health Research Institute, National Institute of Advanced Industrial Science and Technology (AIST), 2217-14 Hayashi-cho, Takamatsu, Kagawa, 761-0395, Japan.
Anal Sci. 2021 Mar 10;37(3):469-473. doi: 10.2116/analsci.20SCP05. Epub 2020 Nov 6.
In this paper, we report on stimuli-responsive behaviors for room temperature fluorescent liquid materials based on N-heteroacene frameworks in response to HCl vapor. These liquid materials as well as their mixtures prepared by varying the combination can provide various emission colors and stimuli-responsive properties in liquid states. Also, we achieved an improvement in total synthetic yield (>40%) by redesigning the molecular structures of liquid materials as compared to previous liquid materials (<10%).
本文报道了基于 N-杂环芳烃骨架的室温荧光液体材料在 HCl 蒸气刺激下的响应行为。这些液体材料及其混合物通过改变组合可以在液体状态下提供各种发射颜色和刺激响应特性。此外,通过重新设计液体材料的分子结构(与之前的液体材料相比(<10%)),我们将总合成产率提高了(>40%)。