Shimada Masanari, Mizuno Hideyuki, Ikeda Atsushi
Graduate School of Arts and Sciences, The University of Tokyo, Tokyo 153-8902, Japan.
Soft Matter. 2021 Jan 22;17(2):346-364. doi: 10.1039/d0sm01583k.
Recently, progress has been made in the understanding of anomalous vibrational excitations in amorphous solids. In the lowest-frequency region, the vibrational spectrum follows a non-Debye quartic law, which persists up to zero frequency without any frequency gap. This gapless vibrational density of states (vDOS) suggests that glasses are on the verge of instability. This feature of marginal stability is now highlighted as a key concept in the theories of glasses. In particular, the elasticity theory based on marginal stability predicts the gapless vDOS. However, this theory yields a quadratic law and not the quartic law. To address this inconsistency, we presented a new type of instability, which is different from the conventional one, and proposed that amorphous solids are marginally stable considering the new instability in the preceding study [M. Shimada, H. Mizuno and A. Ikeda, Soft Matter, 2020, 16, 7279]. In this study, we further extend and detail the results for these instabilities. By analyzing various examples of disorder, we demonstrate that real glasses in finite spatial dimensions can be marginally stable by the proposed novel instability.
最近,在理解非晶态固体中的异常振动激发方面取得了进展。在最低频率区域,振动光谱遵循非德拜四次定律,该定律一直持续到零频率,没有任何频率间隙。这种无间隙的振动态密度(vDOS)表明玻璃处于不稳定的边缘。这种边际稳定性的特征现在被视为玻璃理论中的一个关键概念。特别是,基于边际稳定性的弹性理论预测了无间隙的vDOS。然而,该理论得出的是二次定律,而不是四次定律。为了解决这种不一致性,我们提出了一种新型的不稳定性,它不同于传统的不稳定性,并在前一项研究[M. Shimada, H. Mizuno和A. Ikeda, Soft Matter, 2020, 16, 7279]中提出,考虑到这种新的不稳定性,非晶态固体是边际稳定的。在本研究中,我们进一步扩展并详细阐述了这些不稳定性的结果。通过分析各种无序示例,我们证明了在有限空间维度中的真实玻璃可以通过所提出的新型不稳定性实现边际稳定。