Zheng Qingshu, Borsley Stefan, Tu Tao, Cockroft Scott L
EaStCHEM School of Chemistry, University of Edinburgh, Joseph Black Building, David Brewster Road, Edinburgh EH9 3FJ, UK.
Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Department of Chemistry, Fudan University, 2005 Songhu Road, Shanghai 200438, China.
Chem Commun (Camb). 2020 Nov 24;56(93):14705-14708. doi: 10.1039/d0cc06775j.
We report the reversible chromism and luminescence of a cyclometalated platinum(ii) complex that forms dimers, with close PtPt interactions that can be modulated by solvent and temperature. The precise reversible control may be exploited in future stimuli-responsive chemosensing or optoelectronic devices.
我们报道了一种环金属化铂(II)配合物的可逆变色和发光现象,该配合物形成二聚体,具有紧密的Pt-Pt相互作用,可通过溶剂和温度进行调节。这种精确的可逆控制在未来的刺激响应化学传感或光电器件中可能会得到应用。