Key laboratory of Advanced Functional Materials of Nanjing, Nanjing Xiaozhuang University, Nanjing 211171, P. R. China.
Dalton Trans. 2020 Dec 8;49(46):16643-16648. doi: 10.1039/d0dt02261f.
Two noncentrosymmetric haloplumbate hybrids, [C6H10(NH3)2][PbCl4] (1) and [C6H10(NH3)2][PbBr4] (2), have been synthesized. Crystals of 1 and 2 belong to the chiral space group P212121. The inorganic parts comprise a one-dimensional chain structure for 1 and a two-dimensional sheet structure for 2. Both compounds exhibit thermochromic luminescence originating from dual emission and have potential applications as self-referencing luminescent thermometers.
两种非中心对称卤化铅杂化物，[C6H10(NH3)2][PbCl4]（1）和[C6H10(NH3)2][PbBr4]（2），已经被合成。1 和 2 的晶体属于手性空间群 P212121。无机部分包括 1 的一维链结构和 2 的二维层状结构。这两种化合物都表现出源于双发射的热致变色发光，并有作为自基准发光温度计的潜在应用。
