Huang Li, Zhou Jian
Chongqing Key Laboratory of Inorganic Functional Materials, College of Chemistry, Chongqing Normal University, Chongqing 401331, P. R. China.
Inorg Chem. 2020 Dec 7;59(23):16814-16818. doi: 10.1021/acs.inorgchem.0c02620. Epub 2020 Nov 10.
Two new hybrid polymeric iodoargentates, [AgI(phen)] (; phen = 1,10-phenanthroline) and [AgI(bpt)] (; bpt = 3,5-bis(pyrazinyl)-1,2,4-triazole), were prepared by the hydrothermal methods. displays a new type of taenioid, [AgI(phen)], chain incorporating phen molecules, while exhibits a unique 2D hybrid iodoargentate based on a combination of the [AgI] layer and bpt molecules as electron acceptors. Such a 2D layer is the first example of an inorganic iodoargentate layer covalently bonding to aromatic N-heterocycle derivatives within the iodoargentates. and exhibit photocurrent response properties.
通过水热法制备了两种新型杂化聚合碘银酸盐，[AgI(phen)]（；phen = 1,10 - 菲咯啉）和[AgI(bpt)]（；bpt = 3,5 - 双（吡嗪基）-1,2,4 - 三唑）。[AgI(phen)]呈现出一种新型的带形，[AgI(phen)]链，其中包含菲咯啉分子，而[AgI(bpt)]基于[AgI]层和作为电子受体的bpt分子的组合表现出独特的二维杂化碘银酸盐。这样的二维层是无机碘银酸盐层与碘银酸盐内的芳香族N - 杂环衍生物共价键合的首个例子。[AgI(phen)]和[AgI(bpt)]表现出光电流响应特性。
