Two Hybrid Polymeric Iodoargentates Incorporating Aromatic N-Heterocycle Derivatives as Electron Acceptors.

Two new hybrid polymeric iodoargentates, [AgI(phen)] (; phen = 1,10-phenanthroline) and [AgI(bpt)] (; bpt = 3,5-bis(pyrazinyl)-1,2,4-triazole), were prepared by the hydrothermal methods. displays a new type of taenioid, [AgI(phen)], chain incorporating phen molecules, while exhibits a unique 2D hybrid iodoargentate based on a combination of the [AgI] layer and bpt molecules as electron acceptors. Such a 2D layer is the first example of an inorganic iodoargentate layer covalently bonding to aromatic N-heterocycle derivatives within the iodoargentates. and exhibit photocurrent response properties.