Li Ruizhen, Chen Hanyang, Xiong Jianrong, Xu Xiaoying, Cheng Jiajia, Liu Xingyong, Liu Guo
School of Chemistry and Environmental Engineering, Sichuan University of Science and Engineering, Huixing Rd, Ziliujing District, Zigong 64300, China.
State Environmental Protection Key Laboratory of Synergetic Control and Joint Remediation for Soil & Water Pollution, Chengdu University of Technology, No. 1 Dongsan Road, Er'xian Bridge, Chengdu 610059, China.
Materials (Basel). 2020 Nov 10;13(22):5057. doi: 10.3390/ma13225057.
Recently, the bismuth-based (Bi-based) Z-scheme photocatalysts have been paid great attention due to their good solar energy utilization capacity, the high separation rate of their photogenerated hole-electron pairs, and strong redox ability. They are considerably more promising materials than single semiconductors for alleviating the energy crisis and environmental deterioration by efficiently utilizing sunlight to motivate various photocatalytic reactions for energy production and pollutant removal. In this review, the traits and recent research progress of Bi-based semiconductors and recent achievements in the synthesis methods of Bi-based direct Z-scheme heterojunction photocatalysts are explored. The recent photocatalytic applications development of Bi-based Z-scheme heterojunction photocatalysts in environmental pollutants removal and detection, water splitting, CO reduction, and air (NO) purification are also described concisely. The challenges and future perspective in the studies of Bi-based Z-scheme heterojunction photocatalysts are discussed and summarized in the conclusion of this mini review.
近年来,铋基(Bi基)Z型光催化剂因其良好的太阳能利用能力、光生空穴-电子对的高分离率和强氧化还原能力而备受关注。与单一半导体相比,它们是更具前景的材料,可通过有效利用阳光激发各种光催化反应来生产能源和去除污染物,从而缓解能源危机和环境恶化问题。在这篇综述中,探讨了铋基半导体的特性和最新研究进展,以及铋基直接Z型异质结光催化剂合成方法的最新成果。还简要描述了铋基Z型异质结光催化剂在环境污染物去除与检测、水分解、CO还原和空气(NO)净化方面的光催化应用发展情况。在这篇小型综述的结论部分,讨论并总结了铋基Z型异质结光催化剂研究中的挑战和未来展望。