Silver-based semiconductor Z-scheme photocatalytic systems for environmental purification.

Silver-based semiconductor photocatalysts are promising materials for solving environmental and energy issues due to their strong optical absorption, excellent quantum efficiency and photoelectrochemical properties. However, the uncontrollable photocorrosion and high use cost of single silver-based semiconductor photocatalysts limit its practical application. The construction of Z-scheme photocatalytic systems that mimic natural photosynthesis can not only enhance the photocatalytic activity of silver-based semiconductor photocatalysts, but also improve their stability and reduce the use costs. This critical review concisely highlights the basic principles of Z-scheme photocatalytic systems, and discusses the construction of silver-based semiconductor Z-scheme photocatalytic systems and the roles of metallic Ag in there and summarizes the synthesis methods of silver-based semiconductor Z-scheme photocatalytic systems. Then, a series of the solar-driven applications are elaborated, including organic pollutants degradation, hydrogen production, and carbon dioxide reduction. Meanwhile, the mechanism and difficult level of these photocatalytic reactions are also described. Besides, metal organic frameworks (MOFs) as a novel type of photocatalysts have attracted growing attention. The novel combination of silver-based semiconductors with typical photoactive MOFs is highlighted based on the Z-scheme photocatalytic systems. Eventually, the future challenges and prospects in the development of silver-based semiconductor Z-scheme photocatalytic systems are presented.